O'Danielite
A valid IMA mineral species
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About O'Danielite
Formula:
Na(Zn,Mg)3(AsO4)(AsO3OH)2
Colour:
Pale violet
Lustre:
Vitreous
Hardness:
4
Specific Gravity:
> 4.24
Crystal System:
Monoclinic
Member of:
Name:
Named in 1980 by Keller and Hess in honor of Herbert O'Daniel (7 June 1903, Cologne, German Empire - 15 August 1977, Frankfurt, West Germany), professor of mineralogy, University of Munich, Germany and editor of Neues Jahrbuch fur Mineralogie.
Alluaudite Group. A synthetic Mg analogue is known: 'Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)'.
Ðorðević et al. (2015) published data on the crystal structure of a few synthetic alluaudite-like protonated arsenates, that include the NaZn3(AsO4)(AsO3OH)2 phase. This phase is the synthetic analogue of o'danielite; its structure is based on M1ZnOO4(OH)2 and M2ZnO6 octahedra that share edges to form chains || (101) and linked by the arsenate tetrahedra. The chains form two types of channels || c, one type holding OH groups, and the second one holding Na atoms.
Compare 'Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)'.
Ðorðević et al. (2015) published data on the crystal structure of a few synthetic alluaudite-like protonated arsenates, that include the NaZn3(AsO4)(AsO3OH)2 phase. This phase is the synthetic analogue of o'danielite; its structure is based on M1ZnOO4(OH)2 and M2ZnO6 octahedra that share edges to form chains || (101) and linked by the arsenate tetrahedra. The chains form two types of channels || c, one type holding OH groups, and the second one holding Na atoms.
Compare 'Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)'.
Unique Identifiers
Mindat ID:
2949
Long-form identifier:
mindat:1:1:2949:6
IMA Classification of O'Danielite
Approved
IMA Formula:
Na◻Zn2+Zn2+2(As5+O4)[As5+O3(OH)]2
Approval year:
1979
First published:
1981
Classification of O'Danielite
8.AC.05
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th ed.:
38.2.7.1
20.3.13
20 : Arsenates (also arsenates with phosphate, but without other anions)
3 : Arsenates of Zn, Cd or Hg
20 : Arsenates (also arsenates with phosphate, but without other anions)
3 : Arsenates of Zn, Cd or Hg
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Oda | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of O'Danielite
Vitreous
Transparency:
Translucent
Colour:
Pale violet
Streak:
White
Hardness:
4 on Mohs scale
Hardness Data:
Estimated
Comment:
Handbook of Mineralogy: ~3
Tenacity:
Brittle
Cleavage:
Perfect
{010}, {100} perfect; {001} good?
{010}, {100} perfect; {001} good?
Fracture:
Irregular/Uneven
Density:
> 4.24 g/cm3 (Measured) 4.49 g/cm3 (Calculated)
Optical Data of O'Danielite
Type:
Biaxial (+)
RI values:
nα = 1.745 nβ = 1.753 nγ = 1.778
2V:
Measured: 60° , Calculated: 60°
Birefringence:
0.033
Max. Birefringence:
δ = 0.033
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v moderate
Optical Extinction:
X=b; Y ^ c = 18°
Pleochroism:
Non-pleochroic
Chemistry of O'Danielite
Mindat Formula:
Na(Zn,Mg)3(AsO4)(AsO3OH)2
Element Weights:
Common Impurities:
Mg
Crystallography of O'Danielite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 12.113 Å, b = 12.445 Å, c = 6.793 Å
β = 112.87°
β = 112.87°
Ratio:
a:b:c = 0.973 : 1 : 0.546
Unit Cell V:
943.52 ų (Calculated from Unit Cell)
Z:
4
Comment:
Neues Jahrbuch MM 395 (1988) structure; synthetic material (Ðorðević et al., 2015): a=12.023, b=12.385, c=6.750, β=112.79, V=926.7
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 6.22 Å | (100) |
| 5.59 Å | (50) |
| 3.56 Å | (70) |
| 3.26 Å | (100) |
| 2.78 Å | (80) |
| 2.72 Å | (80) |
| 1.687 Å | (70) |
| 1.664 Å | (60) |
Comments:
ICDD 35-482
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 46 : Near-surface hydrothermal alteration of minerals (see also #22) | |
| 47a : [Near-surface hydration of prior minerals] | |
| 47d : [Arsenates, antimonates, selenates, bismuthinates] |
Type Occurrence of O'Danielite
General Appearance of Type Material:
anhedral grains, flattened on {100} and elongated along [001]; intergrown blades, up to 3 mm
Place of Conservation of Type Material:
University of Stuttgart, Stuttgart, Germany (registration no. NM09); National Museum of Natural History, Washington, D.C., USA (registration no. 145966)
Geological Setting of Type Material:
Oxidized zone of zinc-rich polymetallic ore body.
Associated Minerals at Type Locality:
Synonyms of O'Danielite
Other Language Names for O'Danielite
Relationship of O'Danielite to other Species
Member of:
Other Members of Alluaudite Group:
| Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 | Mon. 2/m : B2/b |
| 'Alluaudite-Ca[]' | ◻4Ca4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : B2/b |
| 'Alluaudite-Na[]' | ◻4Na4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : B2/b |
| Arseniopleite | NaCaMnMn2(AsO4)3 | Mon. 2/m |
| Badalovite | Na2Mg2Fe(AsO4)3 | Mon. 2/m : B2/b |
| Bradaczekite | NaCu4(AsO4)3 | Mon. 2/m : B2/b |
| Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 | Mon. 2/m : B2/b |
| Calciojohillerite | NaCaMg3(AsO4)3 | Mon. 2/m : B2/b |
| Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 | Mon. 2/m : B2/b |
| Canutite | NaMn3[AsO4][AsO3(OH)]2 | Mon. 2/m : B2/b |
| Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 | Mon. 2/m |
| Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O | Mon. 2/m : B2/m |
| Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 | Mon. 2/m : B2/b |
| 'Ferroalluaudite-NaNa' | Na4Na4Fe2+4Fe3+8(PO4)12 | Mon. 2/m : B2/m |
| 'Ferrohagendorfite' | NaCaFe2+Fe2+2(PO4)3 | Mon. |
| Groatite | NaCaMn2(PO4)[PO3(OH)]2 | Mon. 2/m : B2/b |
| Hagendorfite | NaCaMn2+Fe2+2(PO4)3 | Mon. 2/m : B2/b |
| 'Hagendorfite-NaNa' | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) | Mon. 2/m : B2/b |
| Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 | Mon. 2/m : B2/b |
| Johillerite | Na(Mg,Zn)3Cu(AsO4)3 | Mon. 2/m : B2/b |
| Keyite | Cu2+3Zn4Cd2(AsO4)6 · 2H2O | Mon. 2/m : B2/b |
| Khrenovite | Na3Fe3+2(AsO4)3 | Mon. 2/m : B2/b |
| Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 | Mon. 2/m |
| Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] | Mon. 2/m : B2/b |
| Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 | Mon. 2/m : B2/b |
| Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 | Mon. 2/m : B2/b |
| Paraberzeliite | NaCa2Mg2(AsO4)3 | Mon. 2/m : B2/b |
| 'Unnamed (Mn-analogue of Alluaudite)' | (Na,Ca)Mn2+(Mn3+,Fe3+,Fe2+)2(PO4)3 | |
| 'Unnamed (Na-Mg Arsenate Hydroxyarsenate)' | NaMg3(AsO4)(AsO3OH)2 | Mon. 2/m : B2/b |
| 'Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)' | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 | Mon. 2/m : B2/b |
| Varulite | NaCaMn2+Mn2+2(PO4)3 | Mon. 2/m : B2/b |
| Yazganite | NaFe3+2(Mg,Mn2+)(AsO4)3 · H2O | Mon. 2/m : B2/b |
| Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 | Mon. 2/m : P21/c |
| Zincobradaczekite | NaZn2Cu2(AsO4)3 | Mon. 2/m : B2/b |
Common Associates
Associations Based on Photo Data:
| 1 photo of O'Danielite associated with Stranskiite | Zn2Cu(AsO4)2 |
Related Minerals - Strunz-mindat Grouping
| 8.AC. | 'Crocobelonite-1M' | CaFe3+2O(PO4)2 |
| 8.AC. | Magnesioqingheiite | Na2Mg(MgAl)(PO4)3 |
| 8.AC. | Manganobadalovite | NaNaMn(MgFe3+)(AsO4)3 |
| 8.AC. | Yakubovichite | CaNi2Fe3+(PO4)3 |
| 8.AC. | Changesite-(Y) | (Ca8Y)◻Fe2+(PO4)7 |
| 8.AC. | Babunaite-(Nd) | NdAsO4 |
| 8.AC. | Crocobelonite | CaFe3+2O(PO4)2 |
| 8.AC. | Wopmayite | Ca6Na3◻Mn(PO4)3(PO3OH)4 |
| 8.AC. | Beershevaite | CaFe3+3(PO4)3O |
| 8.AC. | Epiebnerite | (NH4)Zn(PO4) |
| 8.AC. | Ebnerite | (NH4)Zn(PO4) |
| 8.AC.X | Dyrnaesite-(La) | Na8Ce4+(La,REE)2(PO4)6 |
| 8.AC. | Edtollite | K2NaCu5Fe3+O2(AsO4)4 |
| 8.AC. | Angarfite | NaFe3+5(PO4)4(OH)4 · 4H2O |
| 8.AC. | Kabalovite | Fe2+3Fe3+4(PO4)6 |
| 8.AC. | Nazarchukite | Ca2NiFe3+2(PO4)4 |
| 8.AC. | Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 |
| 8.AC. | Alumoedtollite | K2NaCu5AlO2(AsO4)4 |
| 8.AC.02 | Grigorievite | Cu3Fe3+2Al2(VO4)6 |
| 8.AC.02 | Koksharovite | CaMg2Fe3+4(VO4)6 |
| 8.AC.02 | Ziminaite | Fe3+ 6 (VO4)6 |
| 8.AC.05 | Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 |
| 8.AC.05 | Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O |
| 8.AC.05 | 'Unnamed (Na-Mg Arsenate Hydroxyarsenate)' | NaMg3(AsO4)(AsO3OH)2 |
| 8.AC.05 | 'Unnamed (Na-Zn-H Arsenate Hydroxyarsenate)' | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 |
| 8.AC.05 | Calciojohillerite | NaCaMg3(AsO4)3 |
| 8.AC.05 | Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 |
| 8.AC.05 va | 'Alluaudite-Na[]' | ◻4Na4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | 'Alluaudite-Ca[]' | ◻4Ca4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | 'Ferroalluaudite-NaNa' | Na4Na4Fe2+4Fe3+8(PO4)12 |
| 8.AC.05 | 'Hagendorfite-NaNa' | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) |
| 8.AC.05 | Howardevansite | NaCuFe2(VO4)3 |
| 8.AC.05 | Khrenovite | Na3Fe3+2(AsO4)3 |
| 8.AC.05 | Zincobradaczekite | NaZn2Cu2(AsO4)3 |
| 8.AC.05 | Paraberzeliite | NaCa2Mg2(AsO4)3 |
| 8.AC.05 | Badalovite | Na2Mg2Fe(AsO4)3 |
| 8.AC.05 | Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] |
| 8.AC.05 | Manganohatertite | NaNaCa(MnFe3+)(AsO4)3 |
| 8.AC.05 | Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 |
| 8.AC.07 | Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 |
| 8.AC.07 | Ferrobobfergusonite | Na2Fe2+5Fe3+Al(PO4)6 |
| 8.AC.10 | Hagendorfite | NaCaMn2+Fe2+2(PO4)3 |
| 8.AC.10 | 'Ferrohagendorfite' | NaCaFe2+Fe2+2(PO4)3 |
| 8.AC.10 | Johillerite | Na(Mg,Zn)3Cu(AsO4)3 |
| 8.AC.10 | Varulite | NaCaMn2+Mn2+2(PO4)3 |
| 8.AC.10 | Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 |
| 8.AC.10 | Arseniopleite | NaCaMnMn2(AsO4)3 |
| 8.AC.10 | Groatite | NaCaMn2(PO4)[PO3(OH)]2 |
| 8.AC.10 | Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 |
| 8.AC.10 | Bradaczekite | NaCu4(AsO4)3 |
| 8.AC.10 | Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 |
| 8.AC.10 | Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 |
| 8.AC.10 | Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 |
| 8.AC.15 | Ferrowyllieite | (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 |
| 8.AC.15 | Qingheiite | NaNaMn2+(MgAl)(PO4)3 |
| 8.AC.15 | Rosemaryite | (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 |
| 8.AC.15 | Ferroqingheiite | NaNaFe2+(MgAl)(PO4)3 |
| 8.AC.15 | Ferrorosemaryite | ◻NaFe2+Fe3+Al(PO4)3 |
| 8.AC.15 | Bobfergusonite | Na2Mn5FeAl(PO4)6 |
| 8.AC.15 | Wyllieite | (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 |
| 8.AC.17 | Czochralskiite | Na4Ca3Mg(PO4)4 |
| 8.AC.18 | Manitobaite | Na16Mn2+ 25Al8(PO4)30 |
| 8.AC.20 | Marićite | NaFe2+(PO4) |
| 8.AC.25 | Schäferite | (NaCa2)Mg2(VO4)3 |
| 8.AC.25 | Berzeliite | (NaCa2)Mg2(AsO4)3 |
| 8.AC.25 | Matyhite | Ca18(Ca,◻)2Fe2+2(PO4)14 |
| 8.AC.25 | Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) |
| 8.AC.25 | Manganberzeliite | (NaCa2)Mn2+2(AsO4)3 |
| 8.AC.25 | Palenzonaite | (NaCa2)Mn2+2(VO4)3 |
| 8.AC.30 | Brianite | Na2CaMg(PO4)2 |
| 8.AC.35 | Vitusite-(Ce) | Na3(Ce,La,Nd)(PO4)2 |
| 8.AC.40 | Bario-olgite | (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · |
| 8.AC.40 | Olgite | (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 |
| 8.AC.45 | Magnesiochangesite-(Ce) | (Ca8Ce)◻Mg(PO4)7 |
| 8.AC.45 | Tuite | Ca3(PO4)2 |
| 8.AC.45 | Ferromerrillite | Ca9NaFe2+(PO4)7 |
| 8.AC.45 | Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) |
| 8.AC.45 | Magnesiochangesite-(Y) | (Ca8Y)◻ Mg(PO4)7 |
| 8.AC.45 | Changesite-(Ce) | (Ca8Ce)◻Fe2+(PO4)7 |
| 8.AC.45 | Merrillite | Ca9NaMg(PO4)7 |
| 8.AC.45 | Whitlockite | Ca9Mg(PO4)6(PO3OH) |
| 8.AC.47 | Iwateite | Na2BaMn(PO4)2 |
| 8.AC.47 | Ozerovaite | Na2KAl3(AsO4)4 |
| 8.AC.47 | Yurmarinite | Na7(Fe3+,Mg,Cu)4(AsO4)6 |
| 8.AC.47 | Pansnerite | K3Na3(Fe3+,Al)6(AsO4)8 |
| 8.AC.47 | Anatolyite | Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 |
| 8.AC.50 | Fillowite | Na3CaMn2+11(PO4)9 |
| 8.AC.50 | Galileiite | Na3Fe2+Fe2+11(PO4)9 |
| 8.AC.50 | Johnsomervilleite | Na3CaFe11(PO4)9 |
| 8.AC.50 | Xenophyllite | Na4Fe2+7(PO4)6 |
| 8.AC.50 | Udinaite | NaMg4(VO4)3 |
| 8.AC.50 | Arsenudinaite | NaMg4(AsO4)3 |
| 8.AC.50 | Chladniite | Na3CaMg11(PO4)9 |
| 8.AC.52 | Lasnierite | (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 |
| 8.AC.55 | Pharmazincite | KZnAsO4 |
| 8.AC.57 | Zubkovaite | Ca3Cu3(AsO4)4 |
| 8.AC.60 | Kosnarite | KZr2(PO4)3 |
| 8.AC.65 | Panethite | (Na,Ca)2(Mg,Fe2+)2(PO4)2 |
| 8.AC.70 | Stanfieldite | Ca4Mg5(PO4)6 |
| 8.AC.75 | Ronneburgite | K2MnV4O12 |
| 8.AC.80 | Tillmannsite | Ag3Hg[(V,As)O4] |
| 8.AC.85 | Filatovite | K(Al,Zn)2(As,Si)2O8 |
Fluorescence of O'Danielite
Not fluorescent.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for O'Danielite
mindat.org URL:
https://www.mindat.org/min-2949.html
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References for O'Danielite
Reference List:
Fleischer, Michael, Chao, George Y., Francis, Carl A., Pabst, and Adolf (1981) New Mineral Names. American Mineralogist, 66 (1-2) 217-220
Fleischer, Michael, Cabri, Louis J. (1981) New Mineral Names. American Mineralogist, 66 (11-12) 1274-1280
Localities for O'Danielite
Showing 1 localities.
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Namibia (TL) | |
| Keller et al. (1981) +1 other reference |
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Tsumeb Mine, Tsumeb, Oshikoto Region, Namibia