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Metaschoderite

A valid IMA mineral species
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About MetaschoderiteHide

Formula:
Al2(PO4)(VO4) · 6H2O
Colour:
Yellowish orange
Hardness:
2
Crystal System:
Monoclinic
Name:
Named as a dehydration product (=meta) of schoderite. The root name is for William Paul Schoder (1900-1977) research chemist, Union Carbide Nuclear Company, for his outstanding contributions to the metallurgy of vanadium.
Dehydration product of schoderite.


Unique IdentifiersHide

Mindat ID:
2683
Long-form identifier:
mindat:1:1:2683:9

IMA Classification of MetaschoderiteHide

Approved
IMA Formula:
Al2(PO4)(V5+O4)·6H2O
Approval year:
1960
First published:
1962
Approval history:
Approved special procedure IMA 1962.
(L2)IMA 24-E: Proposal to change the formula of metaschoderite back to Al2(PO4)(VO4)·6H2O (Erika Kiechle and Thomas Witzke)
Proposal 24-E on metaschoderite is accepted, and the formula of this species is changed back to Al2(PO4)(VO4)·6H2O, according to the original description.

Classification of MetaschoderiteHide

8.CE.70

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5
43.3.1.2

43 : COMPOUND PHOSPHATES, ETC.
3 : Hydrated Normal Compound Phosphates, etc·
21.3.3

21 : Vanadates (and vanadates with arsenate or phosphate)
3 : Vanadates of Al, rare earths, Pb, V or Bi

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MsdrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MetaschoderiteHide

Transparency:
Transparent, Translucent
Colour:
Yellowish orange
Hardness:

Optical Data of MetaschoderiteHide

Type:
Biaxial (+)
RI values:
nα = 1.598 nβ = 1.604 nγ = 1.626
2V:
Measured: 59° , Calculated: 56°
Max. Birefringence:
δ = 0.028
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v weak

Chemistry of MetaschoderiteHide

Mindat Formula:
Al2(PO4)(VO4) · 6H2O
Element Weights:
Element% weight
O60.218 %
Al14.508 %
V13.695 %
P8.327 %
H3.252 %

Calculated from ideal end-member formula.
O
Al
V
P
H

Crystallography of MetaschoderiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P2/m
Setting:
P2/m
Cell Parameters:
a = 11.4 Å, b = 14.9 Å, c = 9.2 Å
β = 79°
Ratio:
a:b:c = 0.765 : 1 : 0.617
Unit Cell V:
1,534.00 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Pseudomorphs after bladed to scaly crystals or spherulitic aggregates.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
14.9 Å(60)
11.1 Å(40)
9.6 Å(15)
7.5 Å(100)
5.68 Å(8)
4.92 Å(10)
3.02 Å(20)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]

Type Occurrence of MetaschoderiteHide

Other Language Names for MetaschoderiteHide

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Metaschoderite associated with VashegyiteAl11(PO4)9(OH)6 · 38H2O
2 photos of Metaschoderite associated with VanoxiteV4+4V5+2O13 · 8H2O
2 photos of Metaschoderite associated with SchoderiteAl2(PO4)(VO4) · 8H2O

Related Minerals - Strunz-mindat GroupingHide

8.CE.MonteneroiteCu2+Mn2+2(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.BelmonteiteCaMn2(AsO4)2 · 7H2OOrth. mm2
8.CE.ZincocabreriteZnMg2(AsO4)2(H2O)8Mon. 2/m : B2/m
8.CE.XBabánekiteCu3(AsO4)2 · 8H2O Mon. 2/m : B2/m
8.CE.05ChudobaiteMg5(AsO4)2(AsO3OH)2 · 10H2OTric. 1 : P1
8.CE.05GeigeriteMn2+5(AsO4)2(HAsO4)2 · 10H2OTric. 1 : P1
8.CE.10NewberyiteMg(PO3OH) · 3H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CE.10ManganonewberyiteMn(PO3OH)(H2O)3Orth. mmm(2/m2/m2/m) : Pbca
8.CE.15Fanguangite(MoO2)(PO3OH) · 4H2OTric. 1 : P1
8.CE.15BrassiteMg(HAsO4) · 4H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CE.20PhosphorrössleriteMg(PO3OH) · 7H2OMon. 2/m : P2/b
8.CE.20RössleriteMg(HAsO4) · 7H2OMon. 2/m : B2/b
8.CE.25SwitzeriteMn2+3(PO4)2 · 7H2OMon. 2/m : P21/b
8.CE.25MetaswitzeriteMn2+3(PO4)2 · 4H2OMon. 2/m : P2/b
8.CE.30PradetiteCoCu4(AsO4)2(HAsO4)2 · 9H2OTric. 1 : P1
8.CE.30VeselovskýiteZnCu4(AsO4)2(HAsO4)2 · 9H2OTric. 1 : P1
8.CE.30LindackeriteCuCu4(AsO4)2(HAsO4)2 · 9H2OTric. 1 : P1
8.CE.30KlajiteMnCu4(AsO4)2(HAsO4)2 · 9-10H2OTric. 1 : P1
8.CE.30Hloušekite(Ni,Co)Cu4(AsO4)2(AsO3OH)2 · 9H2OTric. 1 : P1
8.CE.30OndrušiteCaCu4(AsO4)2(HAsO4)2 · 10H2OTric. 1 : P1
8.CE.35BobierriteMg3(PO4)2 · 8H2OMon. 2/m : B2/b
8.CE.40Barićite(Mg,Fe)3(PO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40ParasymplesiteFe2+3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40GritsenkoiteCoMg2(AsO4)2(H2O)8Mon. 2/m : B2/m
8.CE.40CabreriteNiMg2(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40PakhomovskyiteCo3(PO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40VivianiteFe2+Fe2+2(PO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40ArupiteNi3(PO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40ErythriteCo3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40HörnesiteMg3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40ManganohörnesiteMn2+3(AsO4)2 · 8H2OMon. 2/m : P2/m
8.CE.40KöttigiteZn3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40FerrisymplesiteFe3+3(AsO4)2(OH)3 · 5H2OMon.
8.CE.40AnnabergiteNi3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.45SymplesiteFe2+3(AsO4)2 · 8H2OTric. 1 : P1
8.CE.50CattiiteMg3(PO4)2 · 22H2OTric. 1 : P1
8.CE.55KoninckiteFe3+PO4 · 3H2OTet. 422 : P41212
8.CE.60KaňkiteFeAsO4 · 3.5H2OMon. 2 : P2
8.CE.60HilarioniteFe3+2(SO4)(AsO4)(OH) · 6H2OMon. 2/m : B2/m
8.CE.65SteigeriteAl(VO4) · 3H2OMon. 2/m : P21/m
8.CE.70SchoderiteAl2(PO4)(VO4) · 8H2OMon.
8.CE.75ZigrasiteMgZr(PO4)2 · 4H2OTric. 1 : P1
8.CE.75'UM2009-11-PO:CaHZr'CaZr[PO4]2 · 4H2OTric.
8.CE.75MalhmooditeFeZr(PO4)2 · 4H2OMon. 2/m : P21/b
8.CE.80SantabarbaraiteFe3+3(PO4)2(OH)3 · 5H2OAmor.
8.CE.85Metaköttigite(Zn,Fe,Fe)3(AsO4)2 · 8(H2O,OH)Tric. 1 : P1
8.CE.90SlavkoviteCu13(AsO4)6(AsO3OH)4 · 23H2OTric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MetaschoderiteHide

References for MetaschoderiteHide

Localities for MetaschoderiteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA
 
  • Arkansas
    • Garland County
      • Wilson Springs (Potash Sulfur Springs)
        • Union Carbide Mine
Evans et al. (1984)
  • Nevada
    • Eureka County
      • Gibellini Mining District
[Anthony (1997)
        • Fish Creek Range
Pabst (1979) +3 other references
 
and/or  
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