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Coquandite

A valid IMA mineral species
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About CoquanditeHide

07569060017271922324326.jpg
Henri Coquand
Formula:
Sb6+xO8+x(SO4)(OH)x(H2O)1- x (x = 0.3)
Originally assumed to be (SbO)6(SO4)O2.H2O.
Colour:
Colorless
Lustre:
Adamantine
Hardness:
3 - 4
Specific Gravity:
5.78 (Calculated)
Crystal System:
Triclinic
Name:
In honour of the French scientist Henri Coquand (1811/13-1881), Professor of geology and mineralogy, who carried out extensive studies of the antimony deposits of Tuscany between 1842 and 1849.
This page provides mineralogical data about Coquandite.


Unique IdentifiersHide

Mindat ID:
1125
Long-form identifier:
mindat:1:1:1125:5

IMA Classification of CoquanditeHide

Classification of CoquanditeHide

7.DE.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
E : With only medium-sized cations; unclassified
30.1.18.1

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1
25.8.2

25 : Sulphates
8 : Sulphates of Sb, V, Cr and U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
CqdIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CoquanditeHide

Adamantine
Transparency:
Transparent, Translucent
Colour:
Colorless
Streak:
White
Hardness:
3 - 4 on Mohs scale
Tenacity:
Flexible
Cleavage:
None Observed
Density:
5.78 g/cm3 (Calculated)

Optical Data of CoquanditeHide

Type:
Biaxial (+)
Dispersion:
r < v strong
Comments:
Small size and high RI made optical determinations difficult.

Chemistry of CoquanditeHide

Mindat Formula:
Sb6+xO8+x(SO4)(OH)x(H2O)1- x (x = 0.3)

Originally assumed to be (SbO)6(SO4)O2.H2O.

Crystallography of CoquanditeHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 11.4292(5) Å, b = 29.772(1) Å, c = 11.2989(5) Å
α = 91.152(3)°, β = 119.266(4)°, γ = 92.624(3)°
Ratio:
a:b:c = 0.384 : 1 : 0.38
Unit Cell V:
3,346.44 ų (Calculated from Unit Cell)
Z:
10
Morphology:
Tabular crystals, lamellar, fibers. Elongated along [001] and flattened on {010}.
Twinning:
Polysynthetic twinning with (010) as the twin plane.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020507CoquanditeBindi L, Biagioni C, Ceccantini L, Batoni M, Menchetti S (2014) Coquandite, Sb6+xO8+x(SO4)(OH)x*(H2O)1-x (x=0.3), from the Cetine mine, Tuscany, Italy: crystal structure and revision of the chemical formula Mineralogical Magazine 78 871-8882014Cetine mine, Tuscany, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.3006 Å(100)
3.0573 Å(76)
14.8527 Å(64)
3.1164 Å(51)
3.0863 Å(45)
2.8151 Å(40)
3.1939 Å(28)
3.2010 Å(27)
2.8405 Å(26)
2.7095 Å(25)
Comments:
Data from Bindi et al. (2014).

Geological EnvironmentHide

Type Occurrence of CoquanditeHide

General Appearance of Type Material:
Spheroidal knobs of silky fibres or, rarely, as tiny transparent colourless lamellar crystals on stibnite.
Place of Conservation of Type Material:
National Museum of Natural History, (Smithsonian Institution), Washington D.C., USA.
Museums of Natural History of the Universities of Florence and Pisa, Italy (catalogue numbers l761/RI and 8800, respectively).
Geological Setting of Type Material:
Oxidized stibnite deposit
Associated Minerals at Type Locality:

Synonyms of CoquanditeHide

Other Language Names for CoquanditeHide

German:Coquandit
Spanish:Coquandita

Common AssociatesHide

Associations Based on Photo Data:
16 photos of Coquandite associated with StibniteSb2S3
10 photos of Coquandite associated with Native SulphurS8
5 photos of Coquandite associated with StibiconiteSb3+Sb5+2O6(OH)
4 photos of Coquandite associated with QuartzSiO2
3 photos of Coquandite associated with KlebelsbergiteSb4O4(SO4)(OH)2
1 photo of Coquandite associated with HalotrichiteFe2+Al2(SO4)4 · 22H2O

Related Minerals - Strunz-mindat GroupingHide

7.DE.MagnesioalteriteMg2Fe3+4(SO4)4(C2O4)2(OH)4 · 17H2OMon. 2/m : B2/b
7.DE.FabritziteZn9(SO4)2(OH)12Cl2 · 6H2OTrig. 3 : R3
7.DE.Cossaite(Mg0.5,◻)Al6(SO4)6(HSO4)F6 · 36H2OTrig. 3 : R3
7.DE.DownsiteK2(MoO3)3(SO4) · 4H2OMon. 2/m : B2/m
7.DE.LiangjuniteK2(Mo2O5)(SO4)2 · 3H2OTric. 1 : P1
7.DE.05MangazeiteAl2(SO4)(OH)4 · 3H2OTric.
7.DE.10'UKI-1975-(SO:AlCu)'(Cu, Al, SO4, H2O)
7.DE.10CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2OMon. 2/m : B2/m
7.DE.10CyanotrichiteCu4Al2(SO4)(OH)12 · 2H2OMon. 2/m : B2/m
7.DE.15SchwertmanniteFe3+16(OH,SO4)12-13O16 · 10-12H2OTet.
7.DE.20TlalociteCu10Zn6(Te6+O4)2(Te4+O3)(OH)25Cl · 27H2OOrth.
7.DE.25UtahiteMgCu4Zn2Te6+3O14(OH)4 · 6H2OTric. 1 : P1
7.DE.40OsakaiteZn4(SO4)(OH)6 · 5H2OTric. 1 : P1
7.DE.42AlteriteZn2Fe3+4(SO4)4(C2O4)2(OH)4 · 17H2OMon. 2/m : B2/b
7.DE.45BarrotiteCu9Al(HSiO4)2[(SO4)(HAsO4)0.5](OH)12 · 8H2OTrig. 3
7.DE.45WilcoxiteMgAl(SO4)2F · 17H2OTric. 1 : P1
7.DE.47Tiberiobardiite{Cu9Al[SiO3(OH)]2(OH)12(H2O)6}(SO4)1.5 · 10H2OTrig. 3 : R3
7.DE.50Bouškaite(MoO2)2O(SO3OH)2(H2O)4Tric. 1 : P1
7.DE.50Stanleyite(V4+O)(SO4) · 6H2OOrth.
7.DE.57'Khangalasite'Fe(SO4)(OH) · 2H2OTric.
7.DE.60HydrobasaluminiteAl4(SO4)(OH)10 · 12-36H2OMon.
7.DE.62VolaschioiteFe4(SO4)O2(OH)6 · 2H2OMon. 2/m : B2/m
7.DE.65ZaheriteAl12(SO4)5(OH)26 · 20H2OTric.
7.DE.75CamérolaiteCu6Al3(OH)18(H2O)2[Sb(OH)6](SO4)Tric. 1 : P1

Fluorescence of CoquanditeHide

None observed

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CoquanditeHide

References for CoquanditeHide

Localities for CoquanditeHide

Showing 11 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Plaka
          • Plaka Mines
Rieck et al. (2018)
Italy (TL)
 
  • Tuscany
    • Grosseto Province
      • Scansano
Sabelli et al. (1992)
    • Pisa Province
      • Pomarance
Orlandi (1997) +1 other reference
    • Siena Province
      • Chiusdino
Lapis Magazine Vol 6.1993 Page 22 +1 other reference
Japan
 
  • Ehime Prefecture
    • Saijo City
specimens seen at Kyoto show
Luxembourg
 
  • Canton Wiltz
    • Goesdorf
Filella et al. (2009)
Portugal
 
  • Porto
    • Gondomar
      • Medas
Roper et al. (2015)
Romania
 
  • Maramureș County
Gabor Koller specimens
collected: Gábor Koller
Gábor Koller collection (EDS- and PXRD-analysed by Sándor Szakáll and Béla Fehér)
USA (TL)
 
  • Washington
    • Okanogan County
Sabelli et al. (1992)
 
and/or  
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